Osmosis based power generation
Wednesday, March 19th, 2008Who doesn’t like clever thinking? There are a bunch of ideas which, upon retrospective analysis, you kick yourself for not having thought of first. Recently an osmosis based power generator has been commissioned in Norway by the utility company Statkraft. Osmosis based power generation is essentially to flip the process of desalination via reverse osmosis (RO) membrane filtration.
In RO membrane desalination, salt water is pushed through a membrane which prevents the passage of salt. On one side of the membrane you have clarified water and the other brinier water. The system does not prefer this non-equilibrium state and accordingly the clear water and salt water want to mix back together (this is what is known as a difference in chemical potential on the two sides of the membrane and gives rise to what engineers call osmostic pressure). Because water can flow back through the membrane to remix with the salt solution, energy in the form of pressure must be input to the system to prevent water from flowing back.
In osmotic energy generation, clean water is brought in through the membrane to the salty side. Water easily flows through the membrane to mix with the salty side and generate work. Simple right? Clean, no emissions, and abundant salt water and …
Oh wait… clean, clarified, fresh water is already a challenge to obtain for billions on this earth. You can’t get it everywhere. And if sea level rise, low lying fresh water will become brackish.
The point is that you can’t get something for nothing. This is the lesson that we took from grad schoool in Jeff Tester’s Introduction to Thermodynamics 10.40 class at MIT. In real-world application, there is no such thing as a reversible process. In RO desalination, we fight entropy using work. In osmotic power generation we leverage entropy to create work. It sounds like a perfect strategy if you can create one site to do both the forward and reverse operations (generate energy or clean water when one or the other is required) But between those two steps, we’ll always lose to real-world losses.